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1.
Environ Pollut ; 345: 123418, 2024 Mar 15.
Artigo em Inglês | MEDLINE | ID: mdl-38307243

RESUMO

Measuring the concentration of organochlorine pesticides (OCPs) in agriculture has engaged significant awareness for healthcare investigation since OCPs are harmful to many physiological processes. Excessive usage of these compounds can result in major contamination of the environment and food supply chains. As a result, more accurate and rapid ways to detect pesticide residues in food are required. In this work, we have portrayed the surface-engineered fluorescent blue emissive-carbon dot (B-CD) with a high quantum yield (49.3 %) via the hydrothermal method for fluorescent sensing of OCPs on real samples. The amine group functionalities of carbon dots have supported the direct coordination with -Cl and -OH groups of HEP, ENS, CDF and 2,4-DPAC for the sensitive detection of OCPs, by switching in the fluorescent intensity of B-CD. The functional group of OCPs exhibits a variety of binding interactions with B-CD to contribute a complex formation, which leads to static quenching via an insubstantial restricted electron transfer process. The synthesized carbon dots exhibit individuality in binding nature towards different OCPs. Fluorescence studies help to distinguish the target OCPs and their low detection limits (LODs) were 0.002, 0.099, 0.16 and 0.082 µM for Heptachlor (HEP - turn "on"), Endosulfan (ENS), Chlordimeform (CDF) and 2,4-dichlorophenoxyacetic acid (2,4-DPAC - turn "off") OCPs respectively. The real water samples and agriculture food samples were effectively investigated and the OCP toxicity was noted. Thus, the design of the fluorescence sensor is established as an easy and proficient sensing method for detecting OCPs.


Assuntos
Clorfenamidina , Hidrocarbonetos Clorados , Praguicidas , Carbono , Fluorescência , Monitoramento Ambiental/métodos , Praguicidas/análise , Hidrocarbonetos Clorados/análise
2.
Chemosphere ; 350: 141123, 2024 Feb.
Artigo em Inglês | MEDLINE | ID: mdl-38185426

RESUMO

Pollution is a global menace that poses harmful effects on all the living ecosystems and to the Earth. As years pass by, the available and the looming rate of pollutants increases at a faster rate. Although many treatments and processing strategies are waged for treating such pollutants, the by-products and the wastes or drain off generated by these treatments further engages in the emission of hazardous waste. Innovative and long-lasting solutions are required to address the urgent global issue of hazardous pollutant remediation from contaminated environments. Myco-remediation is a top-down green and eco-friendly tool for pollution management. It is a cost-effective and safer practice of converting pernicious substances into non-toxic forms by the use of fungi. But these pollutants can be transformed into useable products along with multiple benefits for the environment such as sequestration of carbon emissions and also to generate high valuable bioactive materials that fits as a sustainable economic model. The current study has examined the possible applications of fungi in biorefineries and their critical role in the transformation and detoxification of pollutants. The paper offers important insights into using fungal bioremediation for both economically and environmentally sound solutions in the domain of biorefinery applications by combining recent research findings.


Assuntos
Poluentes Ambientais , Biodegradação Ambiental , Ecossistema , Resíduos Perigosos
3.
Environ Pollut ; 342: 123035, 2024 Feb 01.
Artigo em Inglês | MEDLINE | ID: mdl-38030112

RESUMO

Sodium carboxymethyl cellulose polymer was used as a support matrix in immobilizing activated hydrochar derived from bamboo using hydrothermal carbonization. The structural and textural morphology of the beads were studied using FTIR, XRD, SEM/EDS, BET and TGA. Activated hydrochar showed a rough surface with irregular spherical shaped structure. Various oxygenated functional groups in composite beads and activated hydrochar were identified that assist in interaction with PARA pollutant. TGA analysis showed weight loss at three stages 200 °C, 365 °C and 710 °C that leads to complete disintegration of composite beads. BET analysis showed a variation in the surface area between activated hydrochar and beads which could be due to air drying process. Batch adsorption test was conducted for investigating the efficiency of beads in removing PARA from water. Pseudo-second order and Langmuir isotherm fitted the best highlighting chemical mode of adsorption with homogenous interaction on the adsorbent surface. 48.12 mg g-1 was the maximum adsorption capacity estimated from sorption between beads and PARA. For practical applications beads were effectively used in reducing COD levels of PARA spiked sewage water with the defined experimental parameters. Ethanol would be effectively used as regenerating solvent in recycling the beads for the betterment of cost reduction. The activated hydrochar immobilized cellulose beads would be successfully applied as adsorbent in removing target pollutants from water thereby reducing the hurdles faced with respect to fine particles in water treatment.


Assuntos
Esgotos , Poluentes Químicos da Água , Acetaminofen , Celulose , Poluentes Químicos da Água/análise , Concentração de Íons de Hidrogênio , Adsorção , Cinética
4.
Mol Biotechnol ; 2023 Nov 24.
Artigo em Inglês | MEDLINE | ID: mdl-37999921

RESUMO

Fresh water is one of the essential sources of life, and its requirement has increased in the past years due to population growth and industrialization. Industries use huge quantities of fresh water for their processes, and generate high quantities of wastewater rich in organic matter, nitrates, and phosphates. These effluents have contaminated the freshwater sources and there is a need to recycle this wastewater in an ecologically harmless manner. Microalgae use the nutrients in the wastewater as a medium for growth and the biomass produced are rich in nutrition that can cater growing food and energy needs. The primary and secondary metabolites of microalgae are utilized as biofuel and as active ingredients in cosmetics, animal feed, therapeutics, and pharmaceutical products. In this review, we explore food processing industries like dairy, meat, aquaculture, breweries, and their wastewater for the microalgal growth. Current treatment methods are expensive and energy demanding, which indirectly leads to higher greenhouse gas emissions. Microalgae acts as a potential biotreatment tool and mitigates carbon dioxide due to their high photosynthetic efficiency. This review aims to address the need to recycle wastewater generated from such industries and potentiality to use microalgae for biotreatment. This will help to build a circular bioeconomy by using wastewater as a valuable resource to produce valuable products.

5.
Food Res Int ; 173(Pt 2): 113366, 2023 11.
Artigo em Inglês | MEDLINE | ID: mdl-37803705

RESUMO

The food packaging industries are facing the challenge of food waste generation. This can be addressed through the use of edible coating materials. These coatings aid in extending the shelf life of food products, reducing waste. The key components of these coatings include food-grade binding agents, solvents, and fillers. The integration of polysaccharide, protein, lipids, bioactive and composite-based materials with edible coating matrix aids to combat substantial post-harvest loss of highly perishable commodities and elevates the quality of minimally processed food. The aim of this review is to introduce the concept of edible coatings and discuss the different coating materials used in the food industry, along with their properties. Additionally, this review aims to classify the coating types based on characteristic features and explore their application in various food processing industries. This review provides a comprehensive overview of edible coatings, including the integration of polysaccharides, proteins, lipids, bioactive, and composite-based materials into the coating matrix. This review also addresses the significant post-harvest loss of highly perishable commodities and emphasizes the enhancement of quality in minimally processed food. Furthermore, the antimicrobial, anti-corrosive, and edible characteristics are highlighted, showcasing their potential applications in different food packaging industries. Moreover, it also discusses the challenges, safety and regulatory aspects, current trends, and future perspectives, aiming to shed light on the commercialization and future investigation of edible coatings.


Assuntos
Filmes Comestíveis , Eliminação de Resíduos , Embalagem de Alimentos , Conservação de Alimentos , Polissacarídeos/química , Frutas , Proteínas/química , Lipídeos
6.
Environ Res ; 236(Pt 2): 116735, 2023 11 01.
Artigo em Inglês | MEDLINE | ID: mdl-37517489

RESUMO

In the current study, an attempt was made to synthesize coffee husk (CH) activated carbon by chemical modification approach (sulphuric acid-activated CH (SACH) activated carbon) and was used as a valuable and economical sorbent for plausible remediation of Methylene blue (MB) dye. Batch mode trials were carried out by carefully varying the batch experimental variables: SACH activated carbon (SACH AC) dosage, pH, initial dye concentration, temperature, and contact time. The optimum equilibrium time for adsorption by SACH activated carbon was obtained as 60 min, and the maximum adsorption took place at 30 °C. Morphological and elemental composition, crystallinity behaviour, functional groups, and thermal stability were examined using SEM with EDX, XRD, FTIR, BET, TGA, and DTA and these tests showed successful production of activated carbon. The outcomes showed that chemical activation enhanced the number of pores and roughness which possibly maximized the adsorptive potential of coffee husk. The Box-Benken design (BBD) was used to optimize the MB dye adsorption studies and 99.48% MB dye removed at SACH AC dosage of 4.83 g/L at 30 °C for 60 min and pH 8.12, and the maximum adsorption was yielded for sulphuric acid-activated coffee husk carbon carbon with 88.1 mg/g maximum MB adsorption capacity. Langmuir- Freundlich model deliberately provided a better fit to the equilibrium data. The SACH AC-MB dye system kinetics showed a high goodness-of-fit with pseudo second order model, compared to other studied models. Change in Gibbs's free energy (ΔGo) of the system indicated spontaneity whereas low entropy value (ΔSo) suggested that the removal of MB dye on the SACH activated carbon was an enthalpy-driven process. The exothermic nature of the sorption cycle was affirmed by the negative enthalpy value (ΔHo). The adsorptive-desorptive studies reveal that SACH AC could be restored with the maximum adsorption efficiency being conserved after the fifth cycles. Overall, the outcomes revealed that sulphuric acid-activated coffee husk activated carbon (SACH AC) can be used as prompt alternative for low-cost sorbent for treating dye-laden synthetic wastewaters.


Assuntos
Coffea , Poluentes Químicos da Água , Azul de Metileno/análise , Carvão Vegetal , Adsorção , Poluentes Químicos da Água/análise , Concentração de Íons de Hidrogênio , Termodinâmica , Cinética , Água/química
7.
Chemosphere ; 338: 139619, 2023 Oct.
Artigo em Inglês | MEDLINE | ID: mdl-37487975

RESUMO

The electrochemical degradation of alizarin red dye was studied using bismuth oxyhalide attached to bismuth vanadate nanocomposite synthesized via a simple solvothermal method. The electrochemical degradation of alizarin red dye was treated at current densities of 3 and 5 mA cm-1 for 30 min under different supporting electrolyte mediums (NaCl and KCl). Also, the electrochemical degradation of BiOBr/BiVO4 electrode shows higher degradation percentages of 97 and 99 for NaCl and KCl electrolyte solutions, which are higher degradation percentages than pure BiVO4 electrode (88 and 91 for NaCl and KCl). Also, the BiOBr/BiVO4 electrode shows 100% COD reduction during the 30th min of alizarin red dye using both NaCl and KCl electrolyte solutions. This may indicate that the prepared BiOBr/BiVO4 electrode shows an efficient electrode material for the degradation of textile dyes.


Assuntos
Poluentes Ambientais , Águas Residuárias , Bismuto , Cloreto de Sódio , Eletrodos
8.
Environ Pollut ; 333: 122114, 2023 Sep 15.
Artigo em Inglês | MEDLINE | ID: mdl-37379877

RESUMO

Organochlorine pesticides (OCPs) have been used in agriculture, increasing crop yields and representing a serious and persistent global contaminant that is harmful to the environment and human health. OCPs are typically bioaccumulative and persistent chemicals that can spread over long distances. The challenge is to reduce the impacts caused by OCPs, which can be achieved by treating OCPs in an appropriate soil and water environment. Therefore, this report summarizes the process of bioremediation with commercially available OCPs, considering their types, impacts, and characteristics in soil and water sources. The methods explained in this report were considered to be an effective and environmentally friendly technique because they result in the complete transformation of OCPs into a non-toxic end product. This report suggests that the bioremediation process can overcome the challenges and limitations of physical and chemical treatment for OCP removal. Advanced methods such as biosurfactants and genetically modified strains can be used to promote bioremediation of OCPs.


Assuntos
Hidrocarbonetos Clorados , Praguicidas , Poluentes do Solo , Humanos , Biodegradação Ambiental , Poluentes do Solo/análise , Monitoramento Ambiental/métodos , Praguicidas/análise , Hidrocarbonetos Clorados/análise , Solo/química , China
9.
Chemosphere ; 332: 138814, 2023 Aug.
Artigo em Inglês | MEDLINE | ID: mdl-37149102

RESUMO

In this study, simultaneous analysis on electrochemical detection of SMX and TMP in tablet formulation has been made using graphene oxide (GO) and ZnO QDs (GO-ZnO QDs) based nanocomposite modified glassy carbon electrode (GCE). The functional group presence was observed using FTIR study. The electrochemical characterization for GO, ZnO QDs and GO-ZnO QDs was studied using cyclic voltammetry using [Fe(CN)6]3- medium. In order to estimate the electrochemical redox behavior of SMX and TMP from tablet, the developed electrodes GO/GCE, ZnO QDs/GCE and GO-ZnO QDs/GCE are initially tested for electrochemical activity towards the SMX tablet in BR pH 7 medium. Later their electrochemical sensing has been monitored using square wave voltammetry (SWV). On observing the characteristic behavior of developed electrodes, GO/GCE exhibited detection potential of +0.48 V for SMX and +1.37 V for TMP whereas, ZnO QDs/GCE with +0.78V for SMX and for TMP 1.01 V respectively. Similarly, for GO-ZnO QDs/GCE, its 0.45 V for SMX and 1.11 V for TMP are observed using cyclic voltammetry. The obtained potential results on detecting SMX and TMP are in good agreement with previous results. Under optimized conditions, the response has been monitored with linear concentration range 50 µg/L to 300 µg/L for GO/GCE, ZnO QDs/GCE and GO-ZnO QDs/GCE in SMX tablet formulations. Their detection limits for the individual detection using GO-ZnO/GCE for SMX and TMP are found to be 0.252 ng/L and 19.10 µg/L and for GO/GCE it was 0.252 pg/L and 2.059 ng/L respectively. It was observed that ZnO QDs/GCE could not provide the electrochemical sensing towards SMX and TMP which may be due to the ZnO QPs can act as a blocking layer impeding the electron transfer process. Thus, the sensor performance lead to promising biomedical applications in real-time monitoring on evaluating selective analysis with SMX and TMP in tablet formulations.


Assuntos
Grafite , Nanocompostos , Pontos Quânticos , Óxido de Zinco , Carbono/química , Óxido de Zinco/química , Grafite/química , Combinação Trimetoprima e Sulfametoxazol , Eletrodos , Nanocompostos/química , Técnicas Eletroquímicas/métodos
10.
Chemosphere ; 334: 139037, 2023 Sep.
Artigo em Inglês | MEDLINE | ID: mdl-37244559

RESUMO

Palm oil fuel ash (POFA) has limited use as a fertilizer, while contribute effectively to the environmental contamination and health risks. Petroleum sludge poses a serious effect on the ecological environment and human health. The present work aimed to present a novel encapsulation process with POFA binder for treating petroleum sludge. Among 16 polycyclic aromatic hydrocarbons, four compounds were selected for the optimization of encapsulation process due to their high risk as carcinogenic substrates. Percentage PS (10-50%) and curing days (7-28 days) factors were used in the optimization process. The leaching test of PAHs was assessed using a GC-MS. The best operating parameters to minimize PAHs leaching from solidified cubes with OPC and10% POFA were recorded with 10% PS and after 28 days, at which PAH leaching was 4.255 and 0.388 ppm with R2 is 0.90%. Sensitivity analysis of the actual and predicted results for both the control and the test (OPC and 10% POFA) revealed that the actual results of the 10% POFA experiments have a high consistency with the predicted data (R2 0.9881) while R2 in the cement experiments was 0.8009. These differences were explained based on the responses of PAH leaching toward percentage of PS and days of cure. In the OPC encapsulation process, the main role was belonged to PS% (94.22%), while with 10% POFA, PS% contributed by 32.36 and cure day contributed by 66.91%.


Assuntos
Petróleo , Hidrocarbonetos Policíclicos Aromáticos , Humanos , Esgotos/química , Óleo de Palmeira , Hidrocarbonetos Policíclicos Aromáticos/análise , Poluição Ambiental
11.
Chemosphere ; 334: 139014, 2023 Sep.
Artigo em Inglês | MEDLINE | ID: mdl-37224979

RESUMO

A co-precipitation technique has been used to prepare Bismuth tungstate nanoparticles (Bi2WO6) for electrochemical capacitors and electrochemical sensing of Ascorbic acid (AA). Using a scanning rate of 10 mV s -1, the electrode was performed as the pseudocapacitance behavior and the specific capacitance to be up to 677 Fg -1 at 1 A/g. Bi2WO6 versus Glassy carbon electrode (GCE) was also used to study the behavior of the Bi2WO6 modified electrodes in detecting ascorbic acid. This electrochemical sensor shows excellent electrocatalytic performance when ascorbic acid is present, as determined by differential pulse voltammetry. In solution, ascorbic acid diffuses to an electrode surface and controls its surface properties. Based on the results from the investigation, the sensor showed a detection sensitivity of 0.26 mM/mA, and a limit of detection (LOD) of 77.85 mM. It is clear from these results that Bi2WO6 may find application as an electrode material for supercapacitors and glucose sensors.


Assuntos
Nanopartículas Metálicas , Tungstênio , Tungstênio/química , Bismuto , Eletrodos , Nanopartículas Metálicas/química , Ácido Ascórbico/química , Técnicas Eletroquímicas/métodos
12.
Environ Pollut ; 327: 121572, 2023 Jun 15.
Artigo em Inglês | MEDLINE | ID: mdl-37028793

RESUMO

Heavy metals, dyes and pharmaceutical pollutants in water environment are considered as serious threat to the human and animal health globally. Rapid development of industrialization and agricultural activities are the major source for eliminating the toxic pollutants into the aquatic environment. Several conventional treatment methods have been suggested for the removal of emerging contaminants from wastewater. Algal biosorption, among other strategies and techniques, is demonstrating to be a limited technical remedy that is more focused and inherently more efficient and helps remove dangerous contaminants from water sources. The different environmental effects of harmful contaminants, including heavy metals, dyes, and pharmaceutical chemicals, as well as their sources, were briefly compiled in the current review. This paper provides a comprehensive definition of the future possibilities in heavy compound decomposition by using algal technology, from aggregation to numerous biosorption procedures. Functionalized materials produced from algal sources were clearly proposed. This review further highlights the limiting factors of algal biosorption to eliminate the hazardous material. Finally, this study showed how the existence of algae indicates a potential, effective, affordable, and sustainable sorbent biomaterial for minimizing environmental pollution.


Assuntos
Poluentes Ambientais , Metais Pesados , Poluentes Químicos da Água , Purificação da Água , Animais , Humanos , Águas Residuárias , Purificação da Água/métodos , Plantas , Preparações Farmacêuticas
13.
Chemosphere ; 331: 138734, 2023 Aug.
Artigo em Inglês | MEDLINE | ID: mdl-37088205

RESUMO

A biocatalytic membrane offers an ideal alternative to the conventional treatment process for the removal of toxic pentachlorophenol (PCP). The limelight of the study is to utilize superparamagnetic iron oxide nanoparticles (SPIONs) incorporated (poly (methyl vinyl ether-alt-maleic acid) (PMVEAMA) and poly (ether - ether) sulfone (PEES)) membrane for immobilization of laccase and its application towards the removal of PCP. In regard to immobilization of Tramates versicolor laccase onto membranes, 5 mM glutaraldehyde with 10 h cross-linking time was employed, yielding 76.92% and 77.96% activity recovery for PEES/PMVEAMA/La and PEES/PMVEAMA/SPIONs/Lac, respectively. In the context of kinetics and stability studies, the immobilized laccase on PEES/PMVEAMA/Lac membrane outperforms the free and PEES/PMVEAMA laccases. At pH 7.0, the free enzyme loses half of its activity, while the immobilized laccases maintained more than 87% of their initial activity even after 480 min. With regard to PCP removal, the removal efficiency of immobilized laccase on the membrane was more than free enzyme. With 100 ppm of PCP, immobilized laccase on PEES/PMVEAMA/SPIONs membrane at pH 4.0 and 50 °C had a removal efficacy of 61.65% in 24 h. Furthermore, to perk up the removal of PCP, the laccase-aided system with mediators was investigated. Amongst, veratryl alcohol displayed 71.04% of PCP removal using immobilized laccase. The reusability of the laccase heightened after immobilization on PEES/PMVEAMA/SPIONs portraying 62.44% of the residual activity with 39.4% of PCP removal even after five cycles. The current investigation reveals the efficacy of the mediator-aided PEES/PMVEAMA/lac membrane system towards removing PCP from the aqueous solution, which can also be proposed for a membrane bioreactor.


Assuntos
Lacase , Pentaclorofenol , Enzimas Imobilizadas , Ultrafiltração , Polímeros , Concentração de Íons de Hidrogênio
14.
Chemosphere ; 329: 138670, 2023 Jul.
Artigo em Inglês | MEDLINE | ID: mdl-37054843

RESUMO

Decarbonization has become a critical issue in recent years due to rising energy demands and diminishing oil resources. Decarbonization systems based on biotechnology have proven to be a cost-effective and environmentally benign technique of lowering carbon emissions. Bioenergy generation is an environmentally friendly technique for mitigating climate change in the energy industry, and it is predicted to play an important role in lowering global carbon emissions. This review essentially provides a new perspective on the unique biotechnological approaches and strategies based decarbonization pathways. Furthermore, the application of genetically engineered microbes in CO2 biomitigation and energy generation is particularly emphasized. The production of biohydrogen and biomethane via anaerobic digestion techniques has been highlighted in the perspective. In this review, role of microorganisms in bioconversion of CO2 into different types of bioproducts such as biochemical, biopolymers, biosolvents and biosurfactant was summarized. The current analysis, which includes an in-depth discussion of a biotechnology-based roadmap for the bioeconomy, provides a clear picture of sustainability, forthcoming challenges, and perspectives.


Assuntos
Biocombustíveis , Dióxido de Carbono , Dióxido de Carbono/análise , Biotecnologia/métodos
15.
Bioresour Technol ; 378: 128975, 2023 Jun.
Artigo em Inglês | MEDLINE | ID: mdl-36990330

RESUMO

The progress of versatile chemicals and bio-based fuels using renewable biomass has gained ample importance. Furfural and 5-hydroxymethylfurfural are biomass-derived compounds that serve as the cornerstone for high-value chemicals and have a myriad of industrial applications. Despite the significant research into several chemical processes for furanic platform chemicals conversion, the harsh reaction conditions and toxic by-products render their biological conversion an ideal alternative strategy. Although biological conversion confers an array of advantages, these processes have been reviewed less. This review explicates and evaluates notable improvements in the bioconversion of 5-hydroxymethylfurfural and furfural to comprehend the current developments in the biocatalytic transformation of furan. Enzymatic conversion of HMF and furfural to furanic derivative have been explored, while the latter has substantially overlooked a foretime. This discrepancy was reviewed along with the outlook on the potential usage of 5-hydroxymethylfurfural and furfural for the furan-based value-added products' synthesis.


Assuntos
Furaldeído , Furanos , Solventes , Biomassa , Furanos/química
16.
J Biomol Struct Dyn ; 41(23): 14582-14598, 2023.
Artigo em Inglês | MEDLINE | ID: mdl-36974959

RESUMO

Tuberculosis is a highly infectious disease other than HIV/AIDS and it is one of the top ten causes of death worldwide. Resistance development in the bacteria occurs because of genetic alterations, and the molecular insights suggest that the accumulation of mutation in the individual drug target genes is the primary mechanism of multi-drug resistant tuberculosis. Chorismate is an essential structural fragment for the synthesis of aromatic amino acids and synthesized biochemically by a number of bacteria, including Mycobacterium tuberculosis, utilizing the shikimate pathway. This shikimate kinase is the newer possible target for the generation of novel antitubercular drug because this pathway is expressed only in mycobacterium and not in Mammals. The discovery and development of shikimate kinase inhibitors provide an opportunity for the development of novel selective medications. Multiple shikimate kinase inhibitors have been identified via insilico virtual screening and related protein-ligand interactions along with their in-vitro studies. These inhibitors bind to the active site in a similar fashion to shikimate. In the current review, we present an overview of the biology and chemistry of the shikimate kinase protein and its inhibitors, with special emphasis on the various active scaffold against the enzyme. A variety of chemically diversified synthetic scaffolds including Benzothiazoles, Oxadiazoles, Thiobarbiturates, Naphthoquinones, Thiazoleacetonitriles, Hybridized Pyrazolone derivatives, Orthologous biological macromolecule derivatives, Manzamine Alkaloids derivatives, Dipeptide inhibitor, and Chalcones are discussed in detail. These derivatives bind to the specific target appropriately proving their potential ability through different binding interactions and effectively explored as an effective and selective Sk inhibitor.Communicated by Ramaswamy H. Sarma.


Assuntos
Mycobacterium tuberculosis , Ácido Chiquímico , Animais , Ácido Chiquímico/metabolismo , Ácido Chiquímico/farmacologia , Antituberculosos/química , Fosfotransferases (Aceptor do Grupo Álcool)/química , Fosfotransferases (Aceptor do Grupo Álcool)/metabolismo , Inibidores Enzimáticos/química , Mamíferos/metabolismo
17.
Bioresour Technol ; 377: 128958, 2023 Jun.
Artigo em Inglês | MEDLINE | ID: mdl-36965584

RESUMO

This study focuses on using Casuarina equisetifolia biomass for pilot-scale glucose oxidase production from Aspergillus niger and its application in the removal of trace organic contaminants (TrOCs) from municipal wastewater through the bio-Fenton oxidation. The cost of glucose oxidase was 0.005 $/U, including the optimum production parameters, 10% biomass, 7% sucrose, 1% peptone, and 3% CaCO3 at 96 h with an enzyme activity of 670 U/mL. Optimized conditions for H2O2 were 1 M glucose, 100 U/mL glucose oxidase, and 120 mins of incubation, resulting in 544.3 mg/L H2O2. Thus, H2O2 produced under these conditions lead to bio-Fenton oxidation resulting in the removal of 36-92% of nine TrOCs in municipal wastewater at pH 7.0 in 360 mins. Therefore, this work establishes the cost-effective glucose oxidase-producing H2O2 as an attractive bioremediating agent to enhance the removal of TrOCs in wastewater at neutral pH.


Assuntos
Águas Residuárias , Poluentes Químicos da Água , Glucose Oxidase , Biomassa , Peróxido de Hidrogênio , Análise Custo-Benefício , Poluentes Químicos da Água/análise , Oxirredução , Eliminação de Resíduos Líquidos/métodos
18.
Environ Res ; 225: 115570, 2023 05 15.
Artigo em Inglês | MEDLINE | ID: mdl-36868450

RESUMO

An integrated 1D/0D/1D hybrid nanomaterial was prepared from MWCNT supported carbon quantum dots @ MnO2 nanomaterial for a sensitive and selective electrochemical heavy metal ion sensor by hydrothermal methods. The developed nanomaterials were characterized by various analytical methods such as FESEM, HRTEM, XRD, FTIR, EDX and elemental mapping study, and also its electrochemical properties of the prepared samples were investigated by cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) analysis. Differential pulse voltammetry (DPV) analysis has been used to investigate the quantitative detection of heavy metal ions such as cadmium and chromium on modified electrodes under optimal conditions. The in-situ electrochemical sensitivity and selectivity of the samples were determined by varying various parameters, such as the concentration of heavy metal ions, different electrolytes and electrolyte pH. The observed DPV results show that prepared MWCNT (0.05 wt%) and CQD (0.1 wt%) supported MnO2 nanoparticles show effective detection response for chromium (IV) metal ion. In particular, 0D CQD, 1D MWCNT, and MnO2 hybrid nanostructures produced a synergistic effect among them, resulting in strong electrochemical performance of the prepared samples against the target metal ions.


Assuntos
Metais Pesados , Nanoestruturas , Compostos de Manganês/química , Óxidos/química , Íons , Eletrólitos
19.
Chemosphere ; 321: 138115, 2023 Apr.
Artigo em Inglês | MEDLINE | ID: mdl-36775035

RESUMO

The main scope of this study was to compare the efficacy of different advanced oxidation processes (AOPs) combined with adsorption for treating secondary treated effluent of municipal wastewater in a continuous-lab-scale reactor. The results revealed enhanced removal of biological oxygen demand (BOD: C0: 14.1 and Ct: 0 mg L-1 (100%)), chemical oxygen demand (COD: C0: 40.5 and Ct: 4 mg L-1 (≤90%)), and total organic carbon (TOC: C0: 15.2 and Ct: 3.02-3.63 mg L-1 (∼80%)) by UV/PMS, O3/PMS, UV/O3/H2O2, and UV/O3/MnO2 processes followed by glass packed bed reactor (GPBR). Complete inactivation of the bacterial count was observed for all the studied processes. The GPBR showed the additional advantage of termination in the regrowth of bacterial count on the filtering medium. The gas-chromatography and mass spectrometry (GC-MS) analysis showed that AOP followed by adsorption reduced the concentrations of the by-products in the treated effluent. Overall, the synergy between AOP and adsorption improved the effluent quality to meet various indirect potable reuse (IPR) applications.


Assuntos
Poluentes Químicos da Água , Purificação da Água , Águas Residuárias , Peróxido de Hidrogênio/química , Adsorção , Compostos de Manganês , Purificação da Água/métodos , Poluentes Químicos da Água/química , Óxidos , Oxirredução , Raios Ultravioleta , Eliminação de Resíduos Líquidos/métodos
20.
Artigo em Inglês | MEDLINE | ID: mdl-36817164

RESUMO

Management of hospital wastewater is a challenging task, particularly during the situations like coronavirus 2019 (COVID-19) pandemic. The hospital effluent streams are likely to contain many known and unknown contaminants including severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2) along with a variety of pollutants arising from pharmaceuticals, life-style chemicals, drugs, radioactive species, and human excreta from the patients. The effluents are a mixed bag of contaminants with some of them capable of infecting through contact. Hence, it is essential to identify appropriate treatment strategies for hospital waste streams. In this work, various pollutants emerging in the context of COVID-19 are examined. A methodical review is conducted on the occurrence and disinfection methods of SARS-CoV-2 in wastewater. An emphasis is given to the necessity of addressing the challenges of handling hospital effluents dynamically involved during the pandemic scenario to ensure human and environmental safety. A comparative evaluation of disinfection strategies makes it evident that the non-contact methods like ultraviolet irradiation, hydrogen peroxide vapor, and preventive approaches such as the usage of antimicrobial surface coating offer promise in reducing the chance of disease transmission. These methods are also highly efficient in comparison with other strategies. Chemical disinfection strategies such as chlorination may lead to further disinfection byproducts, complicating the treatment processes. An overall analysis of various disinfection methods is presented here, including developing methods such as membrane technologies, highlighting the merits and demerits of each of these processes. Finally, the wastewater surveillance adopted during the COVID-19 outbreak is discussed. Supplementary Information: The online version contains supplementary material available at 10.1007/s13762-023-04803-1.

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